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Divergent asymmetric synthesis of hexahydrobenzophenanthridine dopamine D1 agonists, A-86929, and dihydrexidine

Published in: Journal, Volume : 24, Issue : 5-6, Pages : 278-284

DOI : 10.1016/j.tetasy.2013.02.003

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A divergent and scalable asym. synthesis of the dopamine D1 agonists, A-86929, and dihydrexidine with high diastereo- and enantioselectivity was accomplished from Weinreb amide 8 derived from inexpensive and easily available L-serine. The synthesis of A-86929 involves only one chromatog. purification

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